Chuck (NBC, 8pm) – NEW! Valentine’s Day is disrupted when Team Bartowski is ordered to protect a young heiress in England. Meanwhile, an enigmatic official makes an offer to Casey. Back home, Ellie and Awesome try to sort out a parenting issue; and Morgan mulls over a game-changing move. Guest starring Lauren Cohan, Robin Givens and Mekenna Melvin.
The Cape (NBC, 9pm) – NEW! Conclusion. The Cape must use Dana’s legal connections to attempt to track down the Lich, who is holding a drugged Orwell captive.
Hawaii Five-O (CBS, 10pm) – NEW! Danny gets an unexpected visit from his younger brother, Matt, but Danny soon learns that Matt is the target of an FBI investigation. Meanwhile, a bomber bent on revenge murders a judge’s daughter and the probe leads Steve to believe the man isn’t through killing yet. Guest starring Dane Cook.
Castle (ABC, 10pm) – NEW! Part 1 of 2. The investigation of a murdered cabdriver reveals his involvement in a high-stakes conspiracy, which leads to a federal agent taking charge of the case. Guest starring Adrian Pasdar.
NCIS (CBS, 8pm) – NEW! A marine is murdered and his teeth and fingertips are removed.
NCIS: Los Angeles (CBS, 9pm) – NEW! Deeks is shot when a convenience store is robbed and the investigation centers on whether he was the target or an innocent bystander.
Southland (TNT, 10pm) – NEW! Sammy takes to the desert to find answers; Lydia and Josie keep watch over an alcoholic murder witness; and John and Ben break protocol to help a child.
White Collar (USA, 10pm) – NEW! Peter and Neal work with the U.S. Marshals to identify an FBI agent who’s selling witness locations during trials. Peter finds a lead but decides to protect the agent until he can clear the man’s name.
Criminal Minds (CBS, 9pm) – NEW! The parents of an autistic boy vanish and Reid’s connection with the child could help the agents find his parents. Meanwhile, Prentiss asks two former Interpol colleagues to track down a nemesis from her past.
Criminal Minds: Suspect Behavior (CBS, 10pm) – NEW! The team tracks a killer who targets single businessmen in Cincinnati.
Law & Order: SVU (NBC, 10pm) – NEW! An art patron finds a body, and when detectives question the murdered woman’s good friend and associates, they uncover an antagonistic work environment filled with grown-up bullies. Guest starring LuAnn de Lesseps and Kate Burton.
Justified (FX, 10pm) – NEW! A church bus containing a shipment of painkillers is hijacked, and Boyd is considered the likely suspect. Roots-rock singer Dale Alvin performs in a sequence at a roadhouse, where Raylan is having a tryst with Winona.
CSI (CBS, 9pm) – NEW! Two men pronounced dead suddenly come back to life, leading the CSIs to investigate their mysterious zombie-like existence.
Nikita (CW, 9pm) – NEW! Amanda tries to uncover suspected secrets by interrogating Alex while she is under sedation; Nikita is double-crossed while planning to smuggle Alex out of the country; and Michael sends Birkhoff to investigate Alex.
The Mentalist (CBS, 10pm) – NEW! An antiques dealer is killed in a museum, and a member of the CBI becomes a suspect in the crime.
CSI: NY (CBS, 9pm) – NEW! A conspiracy-obsessed woman is found dead, and the investigation reveals that some of her theories were true.
Fringe (Fox, 9pm) – NEW! The team looks to the past to focus on Walter’s experiments in the 1980s and Olivia’s traumatic experiences.
Blue Bloods (CBS, 10pm) – NEW! A girl is murdered at a debutante ball and the investigation focuses on a prostitute seen with her on a surveillance camera. Meanwhile, Nicky deals with having glimpsed the slain girl when she rode with Danny to the crime scene.
Hawaii Five-O (CBS, 8pm) – A deadly gang war erupts during a high-school football game and Chin discovers that his cousin may be involved. The investigation uncovers a link between the gang and a powerful mainland mob. Meanwhile, Danny’s ex-wife tries to gain full custody of their daughter. Repeat
Cops (Fox, 8pm) – NEW! A Sacramento cop sends his K-9 after a motorcyclist possessing drugs; a man in Pierce County, WA tells police he was attacked by a woman who fought him over a cigarette; three kids are questioned about a rock-throwing incident in Cook County, IL.
Cops (Fox, 8:30pm) – Police in Pahrump, NV use road spikes to halt a suspicious vehicle; officers in Tampa need backup to deal with quarreling neighbors who’ve resorted to gunfire. Repeat
The Mentalist (CBS, 9pm) – In the second-season finale, Jane and Kristina’s first date ends abruptly when a murderer copyiing Red John’s MO strikes. When Kristina tries to contact the real Red John, her life and Jane’s are threatened. Repeat
Law & Order: Los Angeles (NBC, 9pm) – While investigating the death of an oil rig worker, detectives learn that the victim was about to blow the whistle on one of his coworkers. Repeat
America’s Most Wanted (Fox, 9pm) – NEW! Host John Walsh and the U.S. Marshals Service join in an effort to track down the most-wanted fugitive in each of the 50 states. Also: a report one the technology used by law enforcement to combat smuggling and terrorism.
48 Hours Mystery (CBS, 10pm) – NEW! A 15-year-old girl faces a serial killer and lives to tell her story.
Law & Order: SVU (NBC, 10pm) – Stabler speaks at a Take Back the Night rally at his daughter’s college campus, and the rally inspires a woman to accuse a fellow student of rape. Stabler and Benson then investigate the case, and ADA Paxton is assigned to prosecute it. Guest starring Christine Lahti. Repeat
CSI: Miami (CBS, 10pm) – NEW! A high-school bully is stoned to death, and revenge is believed to be the motive as the investigation centers on a group unpopular kids at the school.